| Year | All-Stars (Pos.) |
|---|---|
| 2013 | Brandon Phillips (2B), Joey Votto (1B), Aroldis Chapman (P) |
| 2012 | Joey Votto (1B), Jay Bruce (OF), Aroldis Chapman (P) |
| 2011 | Jay Bruce (OF), Brandon Phillips (2B), Scott Rolen (3B), Joey Votto (1B) |
| 2010 | Brandon Phillips (2B), Arthur Rhodes (P), Scott Rolen (3B), Joey Votto (1B) |
| 2009 | Francisco Cordero (P) |
| 2008 | Edinson Volquez (P) |
| 2007 | Ken Griffey Jr. (OF) |
| 2006 | Bronson Arroyo (P) |
| 2005 | Felipe Lopez (SS) |
| 2004 | Sean Casey (1B), Danny Graves (P), Ken Griffey Jr. (OF), Barry Larkin (SS) |
| 2003 | Aaron Boone (3B) |
| 2002 | Adam Dunn (OF) |
| 2001 | Sean Casey (1B) |
| 2000 | Danny Graves (P), Ken Griffey Jr. (OF), Barry Larkin (SS) |
| 1999 | Sean Casey (1B), Barry Larkin (SS), Scott Williamson (P) |
| 1998 | Bret Boone (2B) |
| 1997 | Barry Larkin (SS) |
| 1996 | Barry Larkin (SS) |
| 1995 | Ron Gant (OF), Barry Larkin (SS), Reggie Sanders (OF), John Smiley (P) |
| 1994 | Barry Larkin (SS), Jose Rijo (P) |
| 1993 | Roberto Kelly (OF), Barry Larkin (SS) |
| 1992 | Norm Charlton (P), Bip Roberts (OF) |
| 1991 | Tom Browning (P), Rob Dibble (P), Barry Larkin (SS), Paul O'neill (OF), Chris Sabo (3B) |
| 1990 | Jack Armstrong (P), Rob Dibble (P), Barry Larkin (SS), Randy Myers (P), Chris Sabo (3B) |
| 1989 | Eric Davis (OF), Barry Larkin (SS), John Franco (P) |
| 1988 | Danny Jackson (P), Barry Larkin (SS), Chris Sabo (3B) |
| 1987 | Eric Davis (OF), Bo Diaz (C), John Franco (P) |
| 1986 | John Franco (P), Dave Parker (OF) |
| 1985 | Dave Parker (OF), Pete Rose (1B) |
| 1984 | Mario Soto (P) |
| 1983 | Johnny Bench (C), Mario Soto (P) |
| 1982 | Dave Concepcion (SS), Tom Hume (P), Mario Soto (P) |
| 1981 | Dave Concepcion (SS), George Foster (OF), Tom Seaver (P) |
| 1980 | Johnny Bench (C), Dave Concepcion (SS), Ken Griffey (OF), Ray Knight (3B) |
| 1979 | Johnny Bench (C), Dave Concepcion (SS), George Foster (OF), Mike LaCoss, (P), Joe Morgan (2B) |
| 1978 | Johnny Bench (C), Dave Concepcion (SS), George Foster (OF), Tom Seaver (P), Joe Morgan (2B), Pete Rose (3B) |
| 1977 | Johnny Bench (C), Dave Concepcion (SS), George Foster (OF), Ken Griffey (OF), Tom Seaver (P), Joe Morgan (2B), Pete Rose (3B) |
| 1976 | Johnny Bench (C), Dave Concepcion (SS), George Foster (OF), Ken Griffey (OF), Tony Perez (1B), Joe Morgan (2B), Pete Rose (3B) |
| 1975 | Johnny Bench (C), Dave Concepcion (SS), Tony Perez (1B), Joe Morgan (2B), Pete Rose (OF) |
| 1974 | Johnny Bench (C), Tony Perez (1B), Joe Morgan (2B), Pete Rose (OF) |
| 1973 | Johnny Bench (C), Jack Billingham (P), Dave Concepcion (SS), Joe Morgan (2B), Pete Rose (OF) |
| 1972 | Johnny Bench (C), Clay Carroll (P), Joe Morgan (2B), Gary Nolan (P) |
| 1971 | Johnny Bench (C), Clay Carroll (P), Lee May (1B), Pete Rose (OF) |
| 1970 | Johnny Bench (C), Jim Merritt (P), Tony Perez (3B), Pete Rose (OF), Wayne Simpson (P) |
| 1969 | Johnny Bench (C), Lee May (1B), Tony Perez (3B), Pete Rose (OF) |
| 1968 | Johnny Bench (C), Leo Cardenas (SS), Tommy Helms (2B), Tony Perez (3B), Pete Rose (OF) |
| 1967 | Tommy Helms (2B), Tony Perez (3B), Pete Rose (OF) |
| 1966 | Leo Cardenas (SS), Billy McCool (P) |
| 1965 | Leo Cardenas (SS), Johnny Edwards (C), Sammy Ellis (P), Jim Maloney (P), Frank Robinson (OF), Pete Rose (2B) |
| 1964 | Leo Cardenas (SS), Johnny Edwards (C) |
| 1963 | Johnny Edwards (C), Jim O'Toole (P) |
| 1962 | Frank Robinson (OF), Bob Purkey (P) |
| 1961 | Joey Jay (P), Eddie Kasko (SS), Bob Purkey (P), Frank Robinson (OF) |
| 1960 | Ed Bailey (C), Bill Henry (P), Vada Pinson (OF) |
| 1959 | Vada Pinson (OF), Frank Robinson (1B), Johnny Temple (2B) |
| 1958 | George Crowe (1B), Bob Purkey (P) |
| 1957 | Ed Bailey (C), Ted Kluszewski (1B), Gus Bell (OF), Don Hoak (3B), Roy McMillan (SS), Joe Nuxhall (P), Frank Robinson (OF), Johnny Temple (2B) |
| 1956 | Ed Bailey (C), Ted Kluszewski (1B), Gus Bell (OF), Brooks Lawrence (P), Roy McMillan (SS), Joe Nuxhall (P), Frank Robinson (OF), Johnny Temple (2B) |
| 1955 | Smoky Burgess (C), Ted Kluszewski (1B), Joe Nuxhall (P) |
| 1954 | Gus Bell (OF), Ted Kluszewski (1B) |
| 1953 | Gus Bell (OF), Ted Kluszewski (1B) |
| 1952 | Grady Hatton (3B) |
| 1951 | Ewell Blackwell (P), Johnny Wyrostek (OF) |
| 1950 | Ewell Blackwell (P), Johnny Wyrostek (OF) |
| 1949 | Ewell Blackwell (P), Walker Cooper (C) |
| 1948 | Ewell Blackwell (P) |
| 1947 | Ewell Blackwell (P), Bert Haas (OF), Eddie Miller (SS) |
| 1946 | Ewell Blackwell (P), Ray Lamanno (C), Eddie Miller (SS) |
| 1945 | Frank McCormick (1B) |
| 1944 | Frank McCormick (1B), Eddie Miller (SS), Ray Mueller (C), Bucky Walters (P) |
| 1943 | Lonny Frey (2B), Frank McCormick (1B), Eddie Miller (SS), Johnny Vander Meer (P) |
| 1942 | Paul Derringer (P), Frank McCormick (1B), Ray Starr (P), Johnny Vander Meer (P), Bucky Walters (P) |
| 1941 | Paul Derringer (P), Lonny Frey (2B), Frank McCormick (1B), Bucky Walters (P) |
| 1940 | Paul Derringer (P), Ernie Lombardi (C), Frank McCormick (1B), Bucky Walters (P) |
| 1939 | Paul Derringer (P), Lonny Frey (2B), Ival Goodman (OF), Ernie Lombardi (C), Frank McCormick (1B), Johnny Vander Meer (P), Bucky Walters (P) |
| 1938 | Paul Derringer (P), Ival Goodman (OF), Ernie Lombardi (C), Frank McCormick (1B), Johnny Vander Meer (P) |
| 1937 | Lee Grissom (P), Ernie Lombardi (C) |
| 1936 | Ernie Lombardi (C), Lew Riggs (3B) |
| 1935 | Paul Derringer (OF) |
| 1933 | Chick Hafey (OF) |
